首页> 外文OA文献 >Bis[4-amino-N-(pyrimidin-2-yl-κN)benzene­sulfonamidato-κN](4,4′-di­methyl-2,2′-bipyridine-κ2 N,N′)cadmium dimethyl­formamide disolvate
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Bis[4-amino-N-(pyrimidin-2-yl-κN)benzene­sulfonamidato-κN](4,4′-di­methyl-2,2′-bipyridine-κ2 N,N′)cadmium dimethyl­formamide disolvate

机译:双[4-氨基-N-(嘧啶-2-基-κN)苯­磺酰胺基-κN](4,4'-二­甲基-2,2'-联吡啶-κ2 N,N')二甲基­甲酰胺二磺酸镉

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摘要

In the title compound, [Cd(C10H9N4O2S)2(C12H12N2)]·2C3H7NO, the CdII ion lies on a twofold rotation axis, is six-coordinated by N atoms, and displays a trigonal–prismatic geometry arising from the two sulfadiazinate ligands and one 4,4′-dimethyl-2,2′-bipyridine ligand. Both ligands are bidentate and coordinate via their N atoms. The O and carbonyl C atoms of the dimethyl­formamide mol­ecule show disorder and were modelled with two different orientations and with site occupancies of 0.584 (10):0.416 (10). The geometry around the sulfadiazine S atom is distorted tetra­hedral. The crystal structure involves N—H⋯O hydrogen bonds which link mol­ecules into a three-dimensional network. Weak C—H⋯O hydrogen bonds are also observed.
机译:在标题化合物[Cd(C10H9N4O2S)2(C12H12N2)]·2C3H7NO中,CdII离子位于两倍旋转轴上,由N原子配位,并显示由两个磺二叠氮酸酯配体和一个4,4'-二甲基-2,2'-联吡啶配体。两个配体都是双齿的并且通过它们的N原子配位。二甲基甲酰胺分子的O和羰基C原子显示无序,并以两个不同的方向和0.584 site(10):0.416(10)的位点建模。磺胺嘧啶S原子周围的几何结构是扭曲的四面体。晶体结构包含N-H = O氢键,可将分子连接成三维网络。还观察到弱的CHOH氢键。

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